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新型改性纳米碳酸钙对天然橡胶的补强作用

Reinforcement Effect of a Novel Modified Nano-CaCO3 on Natural Rubber

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【作者】 贾德民古菊周扬波罗远芳

【Author】 Jia De-min Gu Ju Zhou Yang-bo Luo Yuan-fang(College of Materials Science and Engineering,South China Univ. of Tech.,Guangzhou 510640,Guangdong,China)

【机构】 华南理工大学材料学院华南理工大学材料学院 广东广州510640广东广州510640广东广州510640

【摘要】 制备了一种新型改性纳米碳酸钙M -CaCO3,采用FTIR、TGA和SEM对MCaCO3的结构形态进行了研究 ;同时探讨了其与天然橡胶 (NR)形成的纳米复合材料(NR/M -CaCO3)硫化胶的结构、形态和力学性能 ,并分别与硬脂酸包覆型工业纳米碳酸钙 (CCR)及其与天然橡胶形成的纳米复合材料 (NR/CCR)硫化胶进行比较 ,结果表明 ,M -CaCO3对NR具有显著的补强作用 ,其补强效果远优于CCR .

【Abstract】 A novel kind of modified nano-calcium carbonate (M-CaCO3) was prepared. The structure and morphology of M-CaCO3 were investigated by FTIR,TGA and SEM. The morphology and mechanical properties of the vulcanizates of NR/M-CaCO3 nanocomposite were also investigated. The investigation results of M-CaCO3 and NR/M-CaCO3 were then respectively compared with those of CCR (industrial nano-CaCO3 covered with stearic acid) and NR/CCR. It is found that the reinforcement effect of M-CaCO3 on NR is superior to that of CCR.

【基金】 国家自然科学基金重点资助项目 (5 99330 6 0 )
  • 【文献出处】 华南理工大学学报(自然科学版) ,Journal of South China University of Technology(Natural Science) , 编辑部邮箱 ,2004年03期
  • 【分类号】TQ330
  • 【被引频次】30
  • 【下载频次】503
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