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H2O2/Fe3+系统氧化活性染料废水的研究

Study on oxidation of reactive dye waste water with H2O2/Fe3+

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【作者】 王滨松黄君礼张杰

【Author】 WANG Bin-song~1,HUANG Jun-li~1,ZHANG Jie~2 (1.School of Municipal & Environmental Engineering, Harbin Institute of Technology,Harbin 150090,China; 2.School of Life Science, Northeast Forestry University, Harbin 150040,China)

【机构】 哈尔滨工业大学市政环境工程学院东北林业大学生命科学学院 黑龙江哈尔滨150090黑龙江哈尔滨150090黑龙江哈尔滨150040

【摘要】 采用H2O2/Fe3+系统对商业染料活性红(FN-2BLred)、活性蓝(C-Rblue)和活性黄(C-2Ryellow)配制的废水进行了脱色研究.结果表明,当染料质量浓度为400mg/L时,pH值为2 5,H2O2质量浓度为646mg/L,Fe3+浓度是0 25mmol/L,反应温度在60℃,反应20min,3种活性染料废水的色度去除率均达到99%以上;在以上优化的脱色工艺条件下,通过正交试验以COD去除率为指标确定最佳降解工艺条件.结果表明,初始pH值为2 5,过氧化氢质量浓度对于活性红、活性蓝和活性黄废水分别为850、782、646mg/L,Fe3+浓度为1mmol/L,反应温度为60℃,反应60min.在最优工艺条件下,活性红、活性蓝和活性黄废水的COD去除率分别达到93 6%、94 5%和96 3%.

【Abstract】 Three types of simulated commercial reactive dye waste water, separately prepared with FN-2BL red ,C-R blue, and C-2R yellow, were decolorized with H2O2/Fe3+.The experimental results showed that the colority removal efficiencies were above 99% at pH=2.5,Fe3+ 0.25 mmol/L,H2O2 646 mg/L,20 min and 60 ℃ when the concentration of dye was 400 mg/L. Based on the optimized decolored conditions, the optimum conditions required for degradation, determined by perpendicular test, were pH=2.5,Fe3+1 mmol/L,H2O2 850 mg/L for FN-2BL red,H2O2782 mg/L for C-R blue,H2O2646 mg/L for C-2R yellow,60 ℃,and 60 min. The observed COD removal efficiencies were 93.6%,94.5%, and 96.3% for FN-2BL red, C-R blue, and C-2R yellow, respectively.

【关键词】 活性染料催化氧化色度降解
【Key words】 reactive dyecatalytic oxidationcoloritydegradation
【基金】 黑龙江省自然科学基金资助项目(E01-06).
  • 【文献出处】 哈尔滨商业大学学报(自然科学版) ,Journal of Harbin University of Commerce(Sciences Edition) , 编辑部邮箱 ,2004年06期
  • 【分类号】X703
  • 【被引频次】11
  • 【下载频次】197
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