节点文献

γ-Al₂O₃负载钯催化合成肉桂醛的方法研究

Study on synthesis of cinnamaldehyde catalyzed by Pd（Ⅱ）/γ-Al₂O₃

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 WU Chun~1, KONG Qi~1, HAN Li-juan~2 (1.Chemistry Center, Harbin University of Commerce, Harbin 150076, China; 2.Foodstuff School of Heilingjiang Province,Harbin 150076,China)

【机构】哈尔滨商业大学化学中心；黑龙江省粮食学校黑龙江哈尔滨150076；黑龙江哈尔滨150076；黑龙江哈尔滨150080；

【摘要】制备三丁基锡氢化物、肉桂酰氯及高分子载钯催化剂Pd(Ⅱ)/γ-Al2O3,研究了Pd(Ⅱ)/γ-Al2O3对三丁基锡氢化物还原肉桂酰氯制备肉桂醛反应的催化活性,考察了催化剂的使用寿命.采用正交试验对影响反应的因素进行了考察,确定了最佳催化条件,对反应机理进行了研究和探讨.更多还原

【Abstract】 Prepared tributyltin hydride, cinnamoyl chloride and Pd（Ⅱ）/γ-Al₂O₃.Studied the catalytic activity of Pd（Ⅱ）/γ-Al₂O₃ in the reaction of tributyltin hydride with cinnamoyl chloride for synthesis of cinnamal　dehyde. Investigated the servce life of catalysts. The influence factor of reaction were investigated with orthogonal experimental design and the best catalytic condition was determined by this way.The catalytic mechanism also was studied and discussed.更多还原