【摘要】 由手性配体和无水氯化稀土在四氢呋喃溶液中于室温下反应,合成了4种新手性稀土配合物C28H28P2SmCl3,C12H28N4Sm2Cl6,C9H10NOSmCl2·THF,C9H11NO2SmCl·THF·H2O。反应原料无水氯化稀土是按文献方法合成。所有配合物经检测均具有旋光性,元素分析、IR、UV、热分析表征,可以证明所得配合物是我们所期望的产物,且未见报道。更多还原

【Abstract】 Four new rare earth complexes C28H2SP2SmCl3, Cl2H28N4Sm2Cl6, C9H10NOSmCl2·THF, CgH11NO2SmCl·THF·H2O were synthesized by the reaction of anhydrous LnCl3 with chiral ligands in tetrahydrofuran at room temperature. Anhydrous LnCl3 was prepared by the method described in literature. The optical activity of the four complexes has been identified. The structure of these complexes has been proved by elemental analyses, infrared, UV spectrum. It is concluded that these complexes are what we wanted and have not been reported.更多还原