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复合BaTiO3对聚氨酯基互穿聚合物网络阻尼性能的影响

Influence of barium titanate on the damping properties of interpenetrating polymer networks based nanocomposites

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【作者】 唐冬雁刘莉莉张巨生金政赵连城

【Author】 TANG Dong-yan,LIU Li-li,ZHANG Ju-sheng, JIN Zheng, ZHAO Lian-cheng (1. Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001,China; 2. School of Materials Science and Tech-nology, Harbin Institute of Technology, Harbin 150001)

【机构】 哈尔滨工业大学理学院应用化学系哈尔滨工业大学材料科学与工程学院 黑龙江 哈尔滨 150001 哈尔滨工业大学 材料科学与工程学院黑龙江 哈尔滨 150001黑龙江 哈尔滨 150001

【摘要】 分别采用BaTiO3纳米粉和纤维为填料,以改性的聚氨酯(PU)和不饱和聚酯树脂(UP)制备的互穿聚合物网络(IPNs)为骨架材料,采用在位分散聚合法,制备了均匀性较高BaTiO3/IPNs复合型阻尼材料,并研究了BaTiO3形态及复合量对BaTiO3/IPNs型复合材料阻尼性能的影响。结果表明,复合后材料的阻尼性能,除与无机填料的性质有关,主要受其形态影响,纤维状BaTiO3对复合体系的阻尼损耗因子(tanδ)极值和阻尼损耗模量(E′)峰面积提升较为明显;BaTiO3纳米粉的复合量增加到70%(V/V)),E′增加102倍,且tanδ曲线肩峰和主转变峰的位置均移向高温区,相应明显拓宽了室温区的阻尼损耗因子值。

【Abstract】 Well-dispersed BaTiO3/IPNs damping nanocomposites based on modified polyurethane(PU) and unsaturated polyester resin (UP) interpenetrating polymer networks were prepared by in-situ polymerization process and using BaTiO3 nano powders and fibers as filler. The influences of shapes and amounts of BaTiO3 in system on damping behaviors were studied. The results indicated that, the damping properties of the composites were affected mainly by the shapes of filler besides the kinds of that added. Fiber-shaped BaTiO3 increased the values of loss factor(tanδ) and the peak areas of loss modulus(E") apparently. As the amount of BaTiO3 added into the system increased to 70%(V/V), E"improved 102 times compared with that of pure PU/UP IPNs, and both the shoulder peak and main transitional peak moved toward relative higher temperature ranges. So the values of loss factors at room temperature could been enlarged greatly by the adding of BaTiO3.

  • 【文献出处】 航空材料学报 ,Journal of Aeronautical Materials , 编辑部邮箱 ,2004年05期
  • 【分类号】TB535
  • 【被引频次】9
  • 【下载频次】211
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