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镧离子注入对纯锆耐蚀性的影响

Effect of lanthanum ion implantation on the corrosion behavior of zirconium

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【作者】 彭德全白新德周庆钢陈小文余任泓

【Author】 PENG Dequan BAI Xinde ZHOU Qinggang CHEN Xiaowen YURenhong( Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 )

【机构】 清华大学材料科学与工程系清华大学材料科学与工程系 北京 100084北京 100084北京 100084

【摘要】 为了研究镧离子注入对纯锆耐蚀性的影响,样品表面分别注入了1×1016-1×1017cm-2的镧离子,使用MEVVA源作为注入源,注入能量为40 kv。X光电子谱(XPS)分析了注入样品表面镧的价态,三电极动电位扫描测定了注入样品在0.5 mol/L H2SO4溶液中的极化曲线,通过与空白样(未注入样品)比较可知,镧离子注入后,纯锆样品的耐蚀性大大提高。最后,讨论了耐蚀性提高的机理。

【Abstract】 In order to study the influence of lanthanum ion implantation on the aqueous corrosion behavior of zirconium, specimens were implanted by lanthanum ions with a dose range from 1×1016 to 1×1017cm-2, using MAVVA source at an extracted voltage of 40 kV. The valence of the surface layer was confirmed by X-ray photoemission spectroscopy (XPS) . Three-sweep potentiodynamic polarization measurement was employed to evaluate the aqueous corrosion behavior of zirconium in a 0.5 mol/L H2SO4 solution. It was noted that a significant improvement was achieved in the aqueous corrosion resistance of zirconium implanted with lanthanum ions. The mechanism of the corrosion resistance improvement of the lanthanum-implanted zirconium was also discussed in this paper.

【基金】 国家自然科学基金(No.G2000067207-1)资助
  • 【分类号】TG174.4
  • 【被引频次】3
  • 【下载频次】58
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