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天然沸石负载TiO2光催化降解敌敌畏和对硫磷
Photocatalytic degradation of dichlorvos and parathion with titanium dioxide supported on natural zeolite
【摘要】 以钛酸丁酯为原料 ,以天然沸石作载体负载TiO2 制备光催化剂 ;并采用高压汞灯为光源 ,用负载型TiO2 光催化降解敌敌畏和对硫磷。结果表明 ,浓度为 1 2× 1 0 -4mol/L的农药光照 2h左右可完全被光催化氧化为PO3 -4。同时 ,还研究了合成光催化剂的处理温度、溶液的初始pH值、过氧化氢浓度等对负载TiO2 光催化降解的影响
【Abstract】 Using tetrabutyl titanate as raw material,titanium dioxide photocatalyst supported on natural zeolite were prepared. The high pressure mercury lamp was used as light,the photocatalytic degradation of dichlorvos and parathion by this supported titanium dioxide was studied. The result indicated that pesticide at concentration of 1 2×10 -4 mol/L could be absolutely photocatalytic oxidated to PO 3- 4for about 2 hours. At the same time, the effects of some parameters on the photocatalytic activity, such as the different temperature of photocatalyst, the amount of TiO 2, the initial pH of the solution and the concentration of H 2O 2 were studied.
【Key words】 titanium dioxide; natural zeolite; photocatalytic degradation; dichlorvos; parathion;
- 【文献出处】 环境污染治理技术与设备 ,Techniques and Equipment for Environmental Pollution Control , 编辑部邮箱 ,2004年06期
- 【分类号】X712
- 【被引频次】61
- 【下载频次】513