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北京PM2.5化学物种的质量平衡特征

CHARACTERIZATION OF MASS BALANCE OF PM2.5 CHEMICAL SPECIATION IN BEIJING

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【作者】 杨复沫贺克斌马永亮张强Cadle S HChan TMulawa P A

【Author】 YANG Fu-mo 1 HE Ke-bin 1 MA Yong-liang 1 ZHANG Qiang 1Cadle S H 2 Chan T 2 Mulawa P A 2(1 Department of Environmental Science and Engineering,Tsinghua University,Beijing,100084;2 GM Research & Development Center,Warren MI 48090-9055,USA)

【机构】 清华大学环境科学与工程系GM Research & Development CenterWarren MI 48090-9055USAUSA 北京100084北京100084

【摘要】 以北京 2个采样点连续采集的样品对PM2 5中的元素、水溶性离子和含碳组分进行分析 .车公庄和清华园PM2 5中有机物的含量分别为 2 7 8%和 30 9% ,是含量最丰富的物种 ,其次是二次无机粒子、土壤尘、元素碳和微量元素 .PM2 5中约有 2 4 %的质量未能鉴别成分 ,相关性分析表明 ,含碳物种的估算所引起的偏差可能是主要的原因 .采暖期重污染周和春季沙尘周PM2 5的化学物种构成悬殊 ,反映了季节性变化的源排放和特殊气象条件的综合作用 .

【Abstract】 Weekly PM 2.5 samples were continuously collected at two locations in Beijing,and elements,water soluble ions,and carbonaceous species were measured.Organic material was the most abundant species in PM 2.5 ,with a mass percentage of 27.8% and 30.9% at Chegongzhuang and Qinghuayuan,respectively.It was followed in decreasing order by secondary inorganic particles,soil dust,elemental carbon,and trace elements.About 24% of PM 2.5 mass was not identified in the two sampling sites,most likely due to the error from estimation of carbonaceous speciation.PM 2.5 chemical speciation was very different between the week with heavy pollution in heating season and that with severe dust storm in spring,which resulted from the combination effects of source emission varied with seasons and special meteorological conditions.

【关键词】 化学物种质量平衡PM2.5污染北京
【Key words】 chemical compositionmass balancePM 2.5pollutionBeijing.
【基金】 GM研究和发展中心资助
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,2004年03期
  • 【分类号】X831
  • 【被引频次】114
  • 【下载频次】2549
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