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UV/Fenton氧化-混凝联合工艺处理含酚废水

<title>eatment of Phenol - containing Wastewater by UV/Fenton Oxidation - coagulation Process

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【作者】 刘琼玉李太友陈化琼于丹丹

【Author】 <author>u Qiongyu , Li Taiyou , Chen Huaqiong , Yu Dandan(School of Chemistry and Environmental Engineering,Jianghan University,Hubei Wuhan 430056,China)

【机构】 江汉大学化学与环境工程学院江汉大学化学与环境工程学院 湖北 武汉 430056湖北 武汉 430056湖北 武汉 430056

【摘要】 采用UV/Fenton氧化-混凝联合工艺对模拟苯酚废水进行处理,探讨了UV/Fenton预氧化程度和混凝处理条件对模拟苯酚废水处理效果的影响。结果表明,采用混凝处理,COD去除率仅为14.1%;当UV/Fenton预氧化处理过程中H2O2的质量浓度为150~300mg/L时,废水的混凝性能可提高1.5倍以上;当H2O2质量浓度为450 mg/L、光反应时间为30 min时,采用UV/Fenton氧化-混凝工艺联合处理后COD去除率达82.7%。苯酚废水采用UV/Fenton预氧化处理后,进行混凝处理过程的适宜pH为6.5,混凝剂Fe3+的适宜质量浓度为500 mg/L。

【Abstract】 <abstract>mulated phenol-containing wastewater was treated by UV/Fenton oxidation-coagulation process. The effects of UV/Fenton preoxidation and the coagulation condition on treatment efficiency were explored. The removal rate of COD is only 14.1% in direct coagulation treatment. When the mass concentration of H2O2 is 150 -300 mg/L in preoxidation, the coagulation efficiency is increased by 150% . When the mass concentration of H2O2 is 450 mg/L, the photoreaction time is 30 min, the removal rate of COD by the combined process is 82.7 % . After pretreatment by UV/Fenton oxidation, the optimum wastewater pH for coagulation is 6.5, and the mass concentration of Fe3+ is 500 mg/L.

【基金】 武汉市青年科技晨光计划资助项目(20015005064)
  • 【文献出处】 化工环保 ,Environmental Protection of Chemical Industry , 编辑部邮箱 ,2004年04期
  • 【分类号】X703
  • 【被引频次】28
  • 【下载频次】336
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