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化学沉淀法去除焦化废水中的氨氮
Removal of Ammonia-nitrogen from Coking-plant Wastewater by Chemical Precipitation
【摘要】 采用化学沉淀剂MgCl2 ·6H2 O和Na2 HPO4·12H2 O(或MgHPO4·3H2 O)与焦化废水中的NH+ 4 反应 ,生成磷酸铵镁沉淀。探讨了不同操作条件对氨氮去除率的影响。在pH为 8 5~ 9 5的条件下 ,投加的药剂Mg2 + ∶NH+ 4 ∶PO3 -4(摩尔比 )为 1 4∶1∶0 8时 ,废水氨氮的去除率达 99%以上 ,出水氨氮的质量浓度由 2 0 0 0mg/L降至 15mg/L。
【Abstract】 Magnesium ammonium phosphate precipitate was formed in the treatment of coking-plant wastewater via the reaction of MgCl2·6H2O with Na2HPO4·12H2O or MgHPO4·3H2O.The effects of different operating conditions on the removal of ammonium-nitrogen were examined.The results show that when the wastewater pH is 8.5~9.5 and the mol ratio of Mg2+/NH+4/PO43- is 1.4/1/0.8,the removal rate of ammonium-nitrogen is over 99%,and the mass concentration of ammonium-nitrogen in effluent is reduced from 2000 mg/L to 15 mg/L.
【Key words】 chemical precipitation; coking-plant wastewater; ammonium-nitrogen; wastewater treatment;
- 【文献出处】 化工环保 ,Environmental Protection of Chemical Industry , 编辑部邮箱 ,2004年01期
- 【分类号】X703
- 【被引频次】132
- 【下载频次】617