Effects of alloying side B on Ti-based AB₂ hydrogen storage alloys

【Abstract】 Ti-based AB₂-type hydrogen storage alloys are a group of promising materials, which will probably replace the prevalent rare earth-based AB₅-type alloys and be adopted as the main cathode materials of nickel-metal hydride （Ni-MH） batteries in the near future. Alloying in side B is a major way to improve the performance of Ti-based AB₂-type alloys. Based on recent studies, the effects of alloying elements in side B upon the performance of Ti-based AB₂-type hydrogen storage alloys are systematically reviewed here. These performances are divided into two categories, namely PCI characteristics, including hydrogen storage capacity （HSC）, plateau pressure （PP）, pressure hysteresis （PH） and pressure plateau sloping （PPS）, and electrochemical properties, including discharge capacity （DC）, activation property （AP）, cycling stability （CS） and high-rate dischargeability （HRD）. Furthermore, the existing problems in these investigations and some suggestions for future research are proposed.更多还原