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Effect of Cu2+ concentration on hydrogen fermentation

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【Abstract】 The results of the study on the effect of Cu2+ concentration on hydrogen production using a glucose solution and mixed microorganisms from a 9 2 L laboratory-scale digester operated at 35 ℃ indicated the productions of hydrogen, volatile fatty acids (VFAs), ethanol and biogas were inhibited by the added Cu2+ which caused a reduction in the glucose degradation efficiency. The specific yields of hydrogen, ethanol and acetate decreased with increased Cu2+ concentration in the mixed microorganisms. When the Cu2+ concentration in the mixed microorganisms was almost an constant, the specific yields of hydrogen, ethanol and acetate were very similar. A 50% inhibition of hydrogen yield (EC50) occurred at a Cu2+ dosage of 0 50 mg/L in the present investigation. Cu2+ in the external environment is accumulated in the mixed microorganisms. The Cu2+ speciation, using a sequential extraction technique, showed that the Cu2+ was present mainly bound to organic sites in the mixed microorganisms in the present investigation.

【基金】 Sponsoredby“973”FundamentalScienceProgramofChina (GrantNo .G2 0 0 0 0 2 64 0 2 )and“863”ProjectofChina (GrantNo.2 0 0 1AA5 15 0 3 0 )
  • 【文献出处】 Journal of Harbin Institute of Technology ,哈尔滨工业大学学报(英文版) , 编辑部邮箱 ,2004年01期
  • 【分类号】X172
  • 【被引频次】3
  • 【下载频次】111
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