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烯烃/极性单体共聚催化剂的研究进展
Advances in research on transition metal catalysts for copolymerization of olefin and polar monomer
【摘要】 综述了烯烃和含极性基团的烯类单体共聚催化剂的研究进展后过渡金属催化剂和稀土金属催化剂 对共聚合有较好的催化活性,只要对配体结构进行优化或适当组合螫合配体与过渡金属共享电子,就可得到性能更 好且适合工业生产的催化剂。
【Abstract】 This paper reviewed the advances in studies on catalysts for copolymerization of olefin and olefinic monomer with polar group. Both later transition metal and rare earth metal catalysts possess good catalytic activity to the copolymerization reaction. High performance catalysts suitable to commercial production can be prepared either by optimizing structure of ligand or by properly combining chelating ligand and transition metal atom for sharing electron.
【关键词】 极性单体;
共聚合;
茂金属;
后过渡金属催化剂;
【Key words】 <Keyword>polar monomer; copolymerization; metallocene; later transition metal catalyst;
【Key words】 <Keyword>polar monomer; copolymerization; metallocene; later transition metal catalyst;
【基金】 广东省自然科学基金项目(031598)
- 【文献出处】 合成树脂及塑料 ,China Synthetic Resin and Plastics , 编辑部邮箱 ,2004年05期
- 【分类号】O643.3
- 【下载频次】208