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小粒径无皂阳离子聚苯乙烯胶乳纳米粒子的制备与稳定
Preparation and Stability of Emulsifier-Free Cationic Polystyrene Latex Nanoparticles with Solvothermal Method
【摘要】 采用溶剂热法 ,以AIBA为引发剂引发苯乙烯均聚 ,制得了小粒径的无皂阳离子乳胶纳米粒子。讨论了温度对乳胶粒径、反应时间对转化率的影响以及乳液的抗电解质稳定性 ,结果表明 :采用溶剂热法制得的无皂阳离子聚苯乙烯乳胶粒子粒径约为 2 5nm ,分散均匀 ;随着温度的升高粒径先减小后增大 ;乳液的稳定性好
【Abstract】 Emulsifier-free cationic polystyrene nanoparticles with the diameter about 25nm were prepared using 2,2′-aobis(2-ethylpropionamidine)dihydrochloride as initiator with solvothermal method in acetone-water medium. The results reveal that the particle diameter decreases and then increases, with increasing reaction temperature. The stability of microsphere is good.
【关键词】 胶乳纳米粒子;
溶剂热法;
疏水水化作用;
【Key words】 slvothermal method; atex nanoparticles; ydrophobic interaction;
【Key words】 slvothermal method; atex nanoparticles; ydrophobic interaction;
【基金】 国家自然科学基金资助项目 ( 2 9773 0 0 1);安徽省教育厅自然科学基金资助项目( 2 0 0 3kj14 0 )
- 【文献出处】 合成化学 ,Chinese Journal of Synthetic Chemistry , 编辑部邮箱 ,2004年03期
- 【分类号】O632.7
- 【被引频次】7
- 【下载频次】219