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沉积条件对锂离子电池活化改性炭负极性能的影响
The Influence of Deposition Condition on Petroleum Coke Property of Lithium Ion Battery with Gas-Activation
【摘要】 以二氧化碳活化90min的石油焦为原料,考察不同沉积条件对锂离子二次电池炭负极材料性能的影响,采用三电极体系,以200μA·cm-2电流进行恒流充放电测试电池容量。发现温度为700℃、延长沉积时间、增大苯沉积浓度、标态流量和粒径尺寸均有利于提高电极材料的可逆储锂能力;活化和沉积同时进行不利于电极材料性能的提高;提前通苯可明显提高首次充放电容量。
【Abstract】 In this article,petroleum coke activated 90 min was used as material,the research that how deposition conditions influence the property of lithium ion battery was carried out.Three-electrode-system is used to measure the properties of anodes with the current density 200 μA·cm-1. We find that 700℃,increasing deposition time,concentration,standard gas flow rate and grain size all make the reversible capacity of anode better, activation and deposition at one time make the properties worse. C6H6 Added before deposition can increase the first cycle capacity.
【Key words】 deposition; lithium ion battery; activation; carbon anode; property;
- 【文献出处】 化学与生物工程 , 编辑部邮箱 ,2004年05期
- 【分类号】TM912.9
- 【下载频次】110