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恒能量同步荧光法快速同时测定蒽和9,10-二甲基蒽

Constant-Energy Synchronous Fluorescence Spectrometry for Simultaneous Determination of Anthracene and 9,10-Dimethylanthracene

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【作者】 何立芳林丹丽李耀群

【Author】 HE Li fang 1,2 , LIN Dan li 1, LI Yao qun 1* 1. Department of Chemistry, the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China 2. Department of Chemistry, Longyan College, Longyan 364000, China

【机构】 厦门大学化学化工学院与现代分析科学教育部重点实验室厦门大学化学化工学院与现代分析科学教育部重点实验室 福建厦门361005龙岩学院化学系福建龙岩364000福建厦门361005福建厦门361005

【摘要】 建立了蒽和9,10二甲基蒽的同时恒能量同步荧光分析法。它们的恒能量同步荧光光谱和常规荧光光谱相比,分辨力明显提高。蒽和9,10二甲基蒽的线性范围分别为0~2μg·mL-1和0~5μg·mL-1,检出下限分别为22ng·mL-1和17ng·mL-1,相对标准偏差不大于2%。水样中蒽和9,10二甲基蒽的回收率为85%~103%。该方法简便快速,无需预分离。

【Abstract】 A new method of constant energy synchronous fluorimetry to determine anthracene and 9,10 dimethylanthracene simultaneously is suggested. The spectral resolution of the constant energy synchronous fluorescence spectra of these two compounds was much higher than that of conventional spectra. The linear ranges for anthracene and 9,10 dimethylanthracene were 0 2 μg·mL -1 and 0 5 μg·mL -1 respectively. The detection limits of anthracene and 9,10 dimethylanthracene were 2 2 ng·mL -1 and 1 7 ng·mL -1 respectively, and the relative standard deviation was less than 2%. When the new method was used for the determination of anthracene and 9,10 dimethylanthracene in water samples, the recoveries were in the range of 85% to 103%. This method has proved to be simple and rapid.

【基金】 教育部优秀青年教师基金;国家自然科学基金;福建省自然科学基金资助项目
  • 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2004年11期
  • 【分类号】O657.3
  • 【被引频次】19
  • 【下载频次】287
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