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新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物的合成与光谱性质
Synthesis and Spectral Properties of L-Amino Acid Tailed Porphyrin and Their Zinc (Ⅱ) Complexes
【摘要】 用L 氨基酸和 5 [邻 (2 溴乙氧基 )苯基 ] 1 0 ,1 5 ,2 0 三苯基卟啉为原料合成了三种新型L 氨基酸尾式卟啉及其锌 (Ⅱ )配合物 ,通过元素分析、红外光谱、紫外光谱、化学分析和质谱等对其进行了结构表征。测试并研究了它们在 4 0 0 0～ 4 0 0cm-1 范围内的傅里叶变换红外光谱 ,对主要谱带进行了经验归属
【Abstract】 Three new L amino acid tailed porphyrins and their zinc(Ⅱ) complexes were synthesized by L amino acid and 5 [ o (bromoethoxyl) phenyl] 10,15,20 triphenyl prophyrin. FAB MS, UV Vis, IR, elemental analysis and chemical analysis were used to determine the structures of these porphyrins and their zinc complexes. The FTIR spectra (4 000 400 cm -1 ) of L amino acid tailed porphyrin and its zinc(Ⅱ) complexes were measured and investigated. The major bands have been empirically assigned in comparison with L amino acid tailed porphyrin and its zinc(Ⅱ) complexes.
【Key words】 L amino acid tailed porphyrin； Zinc(Ⅱ) complex； Synthesis； Spectral property；
- 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2004年02期
- 【分类号】O641.4
- 【被引频次】6
- 【下载频次】155