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炸药爆轰合成纳米石墨的红外光谱研究

Infrared Spectroscopy Studies of Nano-graphite Synthesized by Explosive Detonation

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【作者】 文潮金志浩关锦清孙德玉李迅刘晓新林英睿唐仕英周刚林俊德

【Author】 WEN Chao 1,2* ,JIN Zhi-Hao 1,GUAN Jin-Qing 2,SUN De-Yu 2,LI Xun 2,LIU Xiao-Xin 2,LIN Ying-Rui 2,TANG Shi-Ying 2,ZHOU Gang 2,LIN Jun-De 2 [WT5”BX](1. State Key Laboratory for Mechanical Behavior of Metal Materials,Xi′an Jiaotong University,Xi′an 710049,China;2. Northwest Institute of Nuclear Technology,Xi′an 710024,China) [WT5HZ]

【机构】 西安交通大学金属材料强度国家重点实验室西北核技术研究所西北核技术研究所 西安710049西安710024西安710049西安710024

【Abstract】 The nano-graphite powder was prepared by means of detonating of pure TNT(trinitrotoluene) explosives in a steel chamber. X-ray diffraction(XRD) and IR results indicate that the black solid powder which collected from the wall and the bottom of the chamber after the detonation has graphite structure and the average size of the particles of graphite is 1.86—2.58 nm. In the FTIR spectrum,there are two characteristic absorption peaks of graphite at 1 561 and 1 233 cm -1 and two antisymmetrical stretch vibration absorption peaks of CH2 at 2 923 and 2 853 cm -1 ,and one flexural vibration absorption peak of CH2 at 1 467 cm -1 . The vibration absorption peaks of CH2 disappeared when the nano-graphite is treated by acid. From the XRD spectrum and the mechanism of forming nano-graphite,the reason of the vibration absorption peaks of CH2 existing in the FTIR of nano-graphite was discussed. [WT5HZ]

【基金】 国家“九七三”计划 (批准号 :G2 0 0 0 0 2 64 0 3 )资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2004年06期
  • 【分类号】O657.3
  • 【被引频次】17
  • 【下载频次】453
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