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2-巯基喹啉包裹的金纳米颗粒的制备及其电化学性质

Preparation of 2-Quinolinethiol Capped Gold Nanoparticles and Its Electrochemical Properties

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【作者】 李迪李景虹

【Author】 LI Di, LI Jing Hong * (State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China)

【机构】 中国科学院长春应用化学研究所中国科学院长春应用化学研究所 电分析化学国家重点实验室长春130022电分析化学国家重点实验室长春130022

【Abstract】 Quinolinethiol was employed as one stabilizer to produce 8—10 nm gold nanoparticles. UV Vis spectrum confirmed the surface plasmon absorbance and in comparison with alkanethiolate gold nanoparticles with the same size, the blue shift in absorbance peak was interpreted as the free electron transferred from N to gold core. Cyclic voltammograms proved that the reduction potential of 2 quinolinethiol was not altered as it assembled onto gold nanoparticles, however there appeared an obvious hysteresis in oxidation current, which was attributed to the oxidation ability of quinoline reduction product.

【关键词】 喹啉金纳米颗粒电化学
【Key words】 QuinolineGold nanoparticlesElectrochemistry
【基金】 国家杰出青年科学基金 (批准号 :2 0 12 5 5 13 );教育部留学回国人员科研启动基金资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2004年03期
  • 【分类号】TB383
  • 【被引频次】1
  • 【下载频次】293
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