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物理交联聚乙烯醇/羟基末端聚酰胺-胺树型高分子水凝胶的制备与性质研究

Preparation and Properties of Physically Cross-linked Poly(vinyl alcohol)/ Hydroxy-terminated Polyamidoamine Dendrimer Hydrogels

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【作者】 武旭业黄世文张建涛卓仁禧

【Author】 WU Xu-Ye, HUANG Shi-Wen, ZHANG Jian-Tao, ZHUO Ren-Xi * (Key Laboratory of Biomedical Polymers of Minstry of Education, Department of Chemistry, Wuhan University, Wuhan 430072, China)

【机构】 武汉大学化学系生物医用高分子教育部重点实验室生物医用高分子教育部重点实验室 武汉430072武汉430072武汉430072

【Abstract】 Novel physically cross-linked hydrogels, composed of PVA and hydroxy-terminated polyamidoamine(PAMAM) dendrimer G6-OH, were prepared by cyclic freezing/thawing treatment of aqueous solutions containing PVA and G6-OH. FTIR analysis indicates that PAMAM dendrimer G6-OH was successfully introduced into PVA hydrogels. Higher contents of G6-OH in PVA/G6-OH hydrogels resulted in higher swelling ratios, and faster reswelling rates. With the increase of freezing/thawing cyclic times, the swelling ratios and reswelling rates of PVA/G6-OH hydrogels decreased, which is similar to that of physically cross-linked PVA hydrogel.

【基金】 国家重点基础研究发展规划 (批准号 :G19990 64 70 3 );国家自然科学基金 (批准号 :2 0 2 0 40 0 9)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2004年02期
  • 【分类号】O631
  • 【被引频次】27
  • 【下载频次】779
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