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物理交联聚乙烯醇/羟基末端聚酰胺-胺树型高分子水凝胶的制备与性质研究
Preparation and Properties of Physically Cross-linked Poly(vinyl alcohol)/ Hydroxy-terminated Polyamidoamine Dendrimer Hydrogels
【Abstract】 Novel physically cross-linked hydrogels, composed of PVA and hydroxy-terminated polyamidoamine(PAMAM) dendrimer G6-OH, were prepared by cyclic freezing/thawing treatment of aqueous solutions containing PVA and G6-OH. FTIR analysis indicates that PAMAM dendrimer G6-OH was successfully introduced into PVA hydrogels. Higher contents of G6-OH in PVA/G6-OH hydrogels resulted in higher swelling ratios, and faster reswelling rates. With the increase of freezing/thawing cyclic times, the swelling ratios and reswelling rates of PVA/G6-OH hydrogels decreased, which is similar to that of physically cross-linked PVA hydrogel.
【关键词】 水凝胶;
聚乙烯醇;
聚酰胺-胺树型高分子;
冷冻-融溶;
物理交联;
【Key words】 Hydrogel; PVA; Polyamidoamine dendrimer; Freezing-thawing; Physically cross-linked;
【Key words】 Hydrogel; PVA; Polyamidoamine dendrimer; Freezing-thawing; Physically cross-linked;
【基金】 国家重点基础研究发展规划 (批准号 :G19990 64 70 3 );国家自然科学基金 (批准号 :2 0 2 0 40 0 9)资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2004年02期
- 【分类号】O631
- 【被引频次】27
- 【下载频次】779