【摘要】 合成了含硫席夫碱1-苯基-3-甲基-4-(α-呋喃甲酰基)吡唑啉酮-5缩氨基硫脲(HL)及其Ni(Ⅱ),Co(Ⅲ)和Cr(Ⅲ)配合物.元素分析及摩尔电导率表明,新配合物的组成为[NiL2]·C2H5OH,[CoL2]Cl·H2O,[CrL2]Cl·1/2H2O.运用红外光谱、紫外光谱、核磁共振谱和磁矩对配合物进行了表征.抗菌实验表明,配合物具有较强的抗菌生物活性.更多还原

【Abstract】 A new Schiff base containing sulphur,l-phenyl-3-methyl-4-（α-furoyl）pyrazolone-5-thiosemicarbazne（HL）and its Ni（Ⅱ）,Co（Ⅲ）and Cr（Ⅲ） complexes have been synthesized.On the basis of elemental analysis and molar conductance,the general formula of the complexes,·C₂H₅OH,Cl·H₂O and Cl·1/2H₂O,was given.They were characterized by IR,UV-visible,¹H NMR,¹³C NMR and magnetic moments.The results show that the metal ions exhibit six-coordinate and may adopt octahedron geometry in the complexes.The antibacterial test results indicate that they have high antibacterial activities against S. aureus,B.subtillis,E.coli,E.carotovora,and C.flaccumfaciens.更多还原