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纳米PbO2修饰电极电催化氧化性能的研究
Study on Electro-catalytic Oxidation Characteristics of Nano-PbO2 Modified Electrode
【摘要】 利用旋转圆盘电极对纳米PbO2修饰电极的电催化氧化性能进行了初步的研究.实验表明由于电极表面PbO2晶粒呈纳米结构,使纳米PbO2修饰电极表面具有大的比表面积,高的表面活性中心,良好的导电性及宏观隧道效应,使得纳米PbO2修饰电极对苯酚有很好的氧化催化性能,用安培法测定了多种有机物在纳米PbO2修饰电极上的电流响应,实验表明,纳米PbO2修饰电极可以作为分析传感器用于有机化合物的测定中.
【Abstract】 The preliminary electrocatalytic oxidation property of nano PbO2 modified electrode by using rotating disk electrode was discussed. It was demonstrated that the nano PbO2 modified electrode had a large specific area, a high surface active center, a good conductivity and macro tunnel effect because of its nanostructure, and therefore it had a very good catalytic and oxidizing property to the organic compounds. So the current response of many organic compounds on the nano PbO2 modified electrode can be used as analytical sensor in the measurement of the organic compounds.
【Key words】 Nano-PbO2; Modified electrode; Catalytic oxidation; Amperometry;
- 【文献出处】 分子催化 ,Journal of Molecular Catalysis , 编辑部邮箱 ,2004年05期
- 【分类号】O646
- 【被引频次】12
- 【下载频次】262