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时效处理对CrCoMo不锈钢耐蚀性能的影响

EFFECT OF AGING TREATMENT ON CORROSION RESISTENCE OF CrCoMo STAINLESS STEEL

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【作者】 马力阎永贵李小亚

【Author】 MA Li~1, YAN Yong-gui~1, LI Xiao-ya~(2,3)(1. State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Materials Research Institute Qingdao Branch, Qingdao 266071, China;2. College of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai 200030, China;3. Hebei University of Science and Technology, Shijiazhuang 050054, China)

【机构】 海洋腐蚀与防护国家重点实验室洛阳船舶材料研究所青岛分部上海交通大学材料科学与工程学院 青岛266071青岛266071上海200030河北科技大学石家庄050054

【摘要】 采用循环极化和电化学阻抗谱研究了退火状态和时效状态的CrCoMo不锈钢在3.5%NaCl溶液中的腐蚀行为。结果表明,退火态CrCoMo不锈钢经时效处理后点蚀电位负移,钝化膜保护性下降,材料的耐蚀性能降低。其原因是时效处理使得第二相沿晶界析出,材料的组织均匀性变差。

【Abstract】 The corrosion behavior of CrCoMo stainless steel specimens under annealed condition and aged condition was investigated in 3.5% NaCl solution by cyclic polarization curves and electrochemical impedance spectroscopy (EIS). The results showed that the pitting potential of CrCoMo stainless steel shifted negatively and the protection performance of the passive film decreased after aging treatment. The decline of corrosion resistance of aged specimens was due to the precipitation of the second-phase along grain boundaries and inhomogeneity of metallurgical structure.

  • 【文献出处】 腐蚀与防护 ,Corrosion & Protection , 编辑部邮箱 ,2004年09期
  • 【分类号】TG174.22
  • 【被引频次】39
  • 【下载频次】215
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