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运用纳米结构钛钒氧化物制备的高稳定性正极材料(英文)
Highly Stable Cathode Materials Prepared From Mesostructured Ti-V Oxides
【摘要】 采用正十二烷胺作为分子模板制备了具有纳米结构的钛钒复合氧化物.将该复合物加热至330℃时,部分分子模板被消除.测试了该氧化物作为锂电池正极材料的性能,发现引入纳米结构极大地提高了材料的充放电稳定性.
【Abstract】 A mesostructured titanium-vanadium oxide has been synthesized using n-dodecylamine as a template. Thermal treatment at 330 ℃ results in a partial removal of the template. The resulting titanium-vanadium oxide exhibits similar capacity (approximately 400 mAh/g), with but better cycling stability than the control sample prepared in the absence of dodecylamine when used as a cathode in lithium batteries.
【关键词】 模板合成;
纳米结构;
氧化钒;
锂电池;
正极材料;
【Key words】 template synthesis; mesostructure; vanadium oxide; lithium battery; cathode material;
【Key words】 template synthesis; mesostructure; vanadium oxide; lithium battery; cathode material;
【基金】 supportedbytheAdvancedBatteryProgram,OfficeofBasicEnergySciences,USDepartmentofEnergyundercontractNo.DE AC 36 83CH10093.
- 【文献出处】 复旦学报(自然科学版) ,Journal of Fudan University , 编辑部邮箱 ,2004年04期
- 【分类号】TM911
- 【下载频次】154