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固体氧化物燃料电池复合阴极研究

Study on the composite cathode of solid oxide fuel cell

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【作者】 魏楸桐郭瑞松王凤华

【Author】 WEI Qiu-tong, GUO Rui-song, WANG Feng-hua (Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University,Tianjin 300072, China)

【机构】 天津大学先进陶瓷与加工技术教育部重点实验室天津大学先进陶瓷与加工技术教育部重点实验室 天津300072天津300072天津300072

【摘要】 中低温(600~800 ℃)固体氧化物燃料电池是目前研究的主流。降低工作温度虽然能够解决材料选择、热应力、腐蚀等一系列问题,但是导致了阴极性能和阴极效率下降。复合阴极在某种程度上可以改善低温下阴极性能恶化的情况,降低过电位和极化电阻、界面电阻等。介绍了复合阴极的研究理论和研究方法,以及为解决这些问题所进行的阴极复合研究的现状,包括阴极材料与电解质、贵金属材料复合的研究现状,提出了今后的研究方向及应解决的问题。

【Abstract】 Intermediate and low-temperature solid oxide fuel cell is a mainstream of researches in this field currently. Lowering operation temperature can solve a serial of problems, such as material selection, thermal stress and material corrosion. Unfortunately, it makes a degradation of the performance and cathode efficiency. Researches prove that composite cathode can solve the problems and improve the performance and efficiency at lower temperature to a certain extend. It decreases the overpotential, polarization resistance and interfacial resistance, etc. The theoretical foundation, research means and present tendency of composite cathodes of electrolyte-cathode and noble metal-cathode were introduced. The problems that should be solved and future development were presented.

【基金】 “863”项目资助(2001 AA 323090,2002 AA 517013)
  • 【文献出处】 电源技术 ,Chinese Journal of Power Sources , 编辑部邮箱 ,2004年01期
  • 【分类号】TM911.4
  • 【被引频次】16
  • 【下载频次】317
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