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锡基复合氧化物负极材料的研究

Study on the tin-based composite oxide as anode materials for lithium ion batteries

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【作者】 吕成学褚嘉宜翟玉春田彦文

【Author】 Lü Cheng-xue~(1,2),CHU Jia-yi~1 ,ZHAI Yu-chun~1 ,TIAN Yan-wen~1(1.School of Materials and Metallurgy, Northeastern University, Shenyang 110004,China ;2.Teachers College of Shenyang University ,Shenyang 110016,China)

【机构】 东北大学材料与冶金学院东北大学材料与冶金学院 辽宁沈阳110004沈阳大学师范学院辽宁沈阳110016辽宁沈阳110004辽宁沈阳110004

【摘要】 采用共沉淀法制备了SnFeO2.5和SnPbO2两种锡基复合氧化物粉末.XRD分析表明,这两种锡基复合氧化物在26°~28°处都有波峰,属无定形结构;SEM的形貌观察发现SnFeO2.5颗粒分层紧密堆积、团聚在一起,SnPbO2颗粒为棱柱状、表面光滑.将其分别作为Li+电池负极材料的活性物质,利用恒电流电池测试仪研究它们的电化学性能,发现这两种锡基复合氧化物都有较高的电化学容量.

【Abstract】 The two tin-compounded oxide powders, SnFeO2.5 and SnPbO2, were prepared by co-precipitation. It is shown by XRD analysis that the two tin-compounded oxides have wave crest between 26°~28° in character belonging to amorphous structure. It can be observed from the shape of SEM that SnFeO2.5 particles accumulate close on separation and SnPbO2 particle is prism. They were used as anode materials for lithium ion batteries respectively, and their electrochemical properties were tested using constant electric current cell tester. Proved by experiments, the two tin-compounded oxides have high electrochemical capacities.

【基金】 国家重点基础研究发展规划资助项目(G19904690-1);沈阳市科技基金资助项目(102241-06).
  • 【文献出处】 东北师大学报(自然科学版) ,Journal of Northeast Normal University (Natural Science Edition) , 编辑部邮箱 ,2004年04期
  • 【分类号】TM911.11
  • 【被引频次】5
  • 【下载频次】191
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