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壳聚糖复合净水剂处理再生造纸废水的研究

Wastewater Treatment by Composite Chitosan as Biosorbent for Repulped Papermaking Plants

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【作者】 姚淑华石中亮宋守志

【Author】 YAO Shu-hua~1,SHI Zhong-liang~2, SONG Shou-zhi~1 (1. School of Resources & Civil Engineering, Northeastern University, Shenyang 110004, China; 2. Department of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142, China. )

【机构】 东北大学资源与土木工程学院沈阳化工学院应用化学系东北大学资源与土木工程学院 辽宁沈阳 110006辽宁沈阳 110142辽宁沈阳 110006

【摘要】 考察了pH值、壳聚糖用量、搅拌速率及静置时间等对COD去除率的影响,得出了最佳实验条件:pH值6 5~6 7,搅拌速率120r/min,静置时间12h,壳聚糖最佳用量为0 4g/L,在此条件下废水的COD去除率可达66%以上·壳聚糖处理效果明显优于无机混凝剂硫酸铝;将壳聚糖与硫酸铝进行配比制得复合净水剂处理再生造纸废水,可进一步提高COD的去除率,去除率可达到83%以上·该净水剂既可以有较高COD去除率,又可以避免二次污染,有较好的环保效果·

【Abstract】 The wastewater treatment for repulped papermaking plants using chitosan and its compasite chitosan as biosorbents is studied. The effects of pH value, chitosan dosage, stiring speed and resting time on COD removal rate are investigated to obtain the optimal experimental conditions, i.e., pH value range of wastewater:6.5~6.7, stiring speed:120?rpm, resting time:12?hr and chitosan dosage:0.4?g/L. Under the conditions the COD removal rate of wastewater can be over 66%. The results show that the chitosan is obviously superior to the non-organic flocculant Al2(SO43 in biosorption process. Moreover, the chitosan can be used further by combining it with Al2(SO43 in a certain proportion to form a new composite purificant or biosorbent to wastewater treatment for repulped papermaking plants, by which the COD removal rate can be up to 83% even more. It will not only improve the COD removal rate but avoid secondary pollution, with better environment protection effect available.

【基金】 国家"十五"科技攻关项目(2001BA609A 10)
  • 【文献出处】 东北大学学报 ,JOURNAL OF NORTHEASTERN UNIVERSITY , 编辑部邮箱 ,2004年12期
  • 【分类号】X703
  • 【被引频次】25
  • 【下载频次】306
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