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利用焦化工艺处理废塑料技术——添加剂OA的作用

Disposal of Waste Plastics by Coking Processthe Effect of Organic Additive (OA)

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【作者】 余广炜蔡九菊雷勇廖洪强

【Author】 YU Guang-wei~1, CAI Jiu-ju~1, LEI Yong~1, LIAO Hong-qiang~2g 110004, China; 2. Shougang Technical Research Institute, Beijing 100041, China. )

【机构】 东北大学国家环境保护生态工业重点实验室首钢技术研究院 辽宁沈阳  110004辽宁沈阳  110004北京  100041

【摘要】 利用热天平与200kg试验焦炉,研究添加剂(OA)、废塑料(WP)与首炼焦配煤(Coal)的热失重行为以及共焦化的成焦性能·结果表明废塑料、炼焦配煤与添加剂在相互重叠的热解失重温度区间内三者裂解生成的自由基相互作用(即协同效应),影响焦炭质量;添加剂OA、废塑料WP与炼焦配煤按比例1∶2∶97混合共焦化时,添加剂(OA)能够消除添加1%废塑料对焦炭质量产生的负面影响,使焦炭M40增加,M10降低,CSR升高,而CRI降低,具有显著的工业应用前景·

【Abstract】 Using a thermal balance and 200?kg pilot coke-oven, the thermal weight loss behavior and characteristics of the cokes produced from co-coking of waste plastics (WP), organic additive (OA) and the coking coal supplied by SHOUSTEEL in Beijing were studied. The results showed that the synergetic effect arising from the pyrolysis of WP, OA and the coal in their common temperature range of weight loss will affect the quality of coke. Moreover, during co-coking the mixture of 1% WP,2% OA and 97% coking, the addition of 2% OA can eliminate the negative influence of the 1% WP on the quality of coke produced from co-coking, thus resulting in the increase of M40 and CSR and decrease of M10 and CRI obviously. Therefore, the technology proposed will have bright outlook in industrial applications.

【关键词】 塑料添加剂热失重焦化协同效应
【Key words】 plasticscoalorganic additivethermal weight losscokingsynergistic effect
【基金】 国家自然科学基金资助项目(50334020);北京市科委资助项目(H020620330310)·
  • 【文献出处】 东北大学学报 ,JOURNAL OF NORTHEASTERN UNIVERSITY , 编辑部邮箱 ,2004年10期
  • 【分类号】X705
  • 【被引频次】2
  • 【下载频次】193
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