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硫、磷系添加剂在菜子油中的响应性

Response Characteristics of 3 Sulfur/Phosphorus System Lubricant Additives in Rapeseed Oil

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【作者】 马江波胡俊宏丁津原马先贵

【Author】 MA Jiang-bo, HU Jun-hong, DING Jin-yuan, MA Xian-gui(School of Mechanical Engineering & Automation, Northeastern University, Shenyang 110004, China. Correspondent: MA Jiang-bo, E-mail: symjb @ 263.net)

【机构】 东北大学机械工程与自动化学院东北大学机械工程与自动化学院 辽宁沈阳 110004辽宁沈阳 110004辽宁沈阳 110004

【摘要】 以菜子油为基础油,在四球摩擦磨损实验机上分别考察了硫系添加剂T321与T307以及磷系添加剂P120对菜子油的耐磨性和极压性能的影响·结果表明,在菜子油中分别加入T321、P120和T307能够降低磨损、提高润滑油膜的承载能力和极压载荷·对钢球表面的能谱分析结果表明,在摩擦磨损过程中,含上述添加剂的菜子油在摩擦过程中发生了摩擦化学变化,生成了由菜子油三甘油酯和添加剂化学产物组成的边界润滑膜,从而改善抗磨性能并提高承载能力·

【Abstract】 Taking rapeseed oil as base constituent, the three lubricant additives, ie. sulfur-system T321 and T307 and phosphorus-system P120, were investigated separately on a 4-ball friction-wear tester with the intention of how they improve the wearability and extreme pressure characteristics of rapeseed oil. The results showed that they all are beneficial to reduce wear-out and improve the load capacity and resistance to extreme pressure of lubrication film. The SEDX(Spectral Energy Distribution X-ray) analysis of steel ball surfaces revealed that there are tribochemical reactions of the rapeseed oil containing any of the three additives during friction/wear process, thus forming a boundary lubrication film composed of triglyceride and others produced from the reacted additive to improve the wearability and load capacity.

【基金】 国家自然科学基金资助项目(59475034);辽宁省教育厅资助项目(202243215)
  • 【文献出处】 东北大学学报 ,JOURNAL OF NORTHEASTERN UNIVERSITY , 编辑部邮箱 ,2004年02期
  • 【分类号】TS221
  • 【被引频次】12
  • 【下载频次】76
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