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热压快速凝固Fe0.92Mn0.08Six半导体的热电性能

Transport Properties of Fe0.92Mn(0.08)Six Semiconductor Prepared by Rapid Solidification and Hot Pressing

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【作者】 芦玉峰赵新兵倪华良陈海燕邬震泰

【Author】 Lu Yufeng,Zhao Xinbing,Ni Hualiang,Chen Haiyan,Wu Zhentai(State Key Laboratory of Silicon Materials,Department of Materials Science and Engineering,Zhejiang University,Hangzhou 310027,China)

【机构】 浙江大学浙江大学 浙江杭州310027浙江杭州310027浙江杭州310027

【摘要】 采用快速凝固和热压的方法制备了p型热电材料Fe0.92Mn0.08Six(x=1.9,2.0,2.1,2.3,2.5)。X射线衍射分析表明,热压试样退火24h后,完全转变为半导体相。所有试样的致密度均高于90%。测量试样的电学性能发现,原料配比为Fe0.92Mn0.08Si2.1的试样在整个测量温度范围内的功率因子最大,550℃时达到了400Wm-1K-1以上。

【Abstract】 P-type Fe0.92Mn0.08Six( x=1.9, 2.0, 2.1, 2.3, 2.5 ) alloys were prepared by rapid solidification and hot pressing. XRD analysis revealed that for all samples the phases were converted into a single b phase after being annealed for 24 h at 800℃. The density of all the samples is over 90%. The experimental results showed that Fe0.92Mn0.08Si2.1 had the highest power factor over the whole measured temperature range greater than 400 mWm-1K-1at 550℃.

【基金】 国家自然科学基金项目(59971004)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2004年09期
  • 【分类号】TN304
  • 【被引频次】5
  • 【下载频次】127
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