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氯化聚丙烯接枝改性胶粘剂的合成及粘接性能研究
Study on Synthesis and Adhesion Property of Graft Modified Chlorinated Polypropylene Adhesive
【摘要】 以甲苯为溶剂,过氧化二苯甲酰(BPO)为引发剂,采用甲基丙烯酸羟乙酯(HEMA)通过自由基聚合接枝对氯化聚丙烯(CPP)进行了改性。研究了反应温度、反应时间、引发剂用量、单体用量对氯化聚丙烯改性胶粘剂粘接性能的影响,并对接枝产物进行了FTIR表征,确定出较理想的工艺条件为反应温度θ=110℃,反应时间t=4h,m(CPP):m(HEMA):m(BPO)=1:1:0.1。
【Abstract】 s:Chlorinated polypropylene grafted by hydroxylethyl methacrylate was prepared by free radical processs in presence of toluence as solvent and benzoperoxide as initiator.The influence of reaction temperature, reaction time and dosage of HEMA and BPO on adhesion property were studied and the product was characterized with FTIR. Optimized reaction conditions were defermined as reaction temperature T=110℃, reaction time t=4h and mass ratio m(CPP):m(HEMA):m(BPO)=1:1:0.1.
【关键词】 氯化聚丙烯;
甲基丙烯酸羟乙酯;
过氧化二苯甲酰;
粘接;
【Key words】 Chlorinated polypropylene; Hydroxylethyl methacrylate; Benzoperoxide; Adhesion;
【Key words】 Chlorinated polypropylene; Hydroxylethyl methacrylate; Benzoperoxide; Adhesion;
- 【文献出处】 材料开发与应用 ,Development and Application of Materials , 编辑部邮箱 ,2004年06期
- 【分类号】TQ433.436
- 【被引频次】11
- 【下载频次】290