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碳纳米管的空气和二氧化碳活化及其对双电层电容器性能的改进

Activation of Carbon Nanotubes by Air and CO2 and its Effect on Electric Double Layer Capacitors

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【作者】 李辰砂李贵涛田秋张世骥田丰王大志曹茂盛

【Author】 LI Chen-sha~1,LI Gui-tao~1,TIAN Qiu~2,ZHANG Shi-ji~1, TIAN Feng~3,WANG Da-zhi~1,CAO Mao-sheng~1(1 Tsinghua University, Beijing 100084,China;2 Harbin Engineering University,Harbin 150001,China; 3 Heihe Entry & Exit Inspection & Quarantine Bureau,Heihe 164300,China)

【机构】 清华大学哈尔滨工程大学黑河出入境检验检疫局清华大学 北京100084北京100084哈尔滨150001黑河164300北京100084

【摘要】 对碳纳米管粉体在高温下进行空气和二氧化碳活化处理,并用于制作双电层电容器极板。结果显示:空气和二氧化碳活化可以有效的剥离和消除非晶碳,打开缠绕成团的管束和碳管端帽,腐蚀管壁,提高粉体分散性,改变碳纳米管的本征结构,使碳纳米管的比表面积增加。由活化后的碳纳米管制成的双电层电容器的比电容明显提高,等效串联电阻下降,性能得以改进。

【Abstract】 Carbon Nanotubes (CNTs) were activated by CO2 and air under different durations, then were used in polarizable electrodes of electric double-layer capacitors (EDLCs). Experiment results indicated that air and CO2 activation could modify intrinsic structures and improve dispersity of CNTs. Specific capacitance of EDLCs based on activated CNTs were obviously improved and the equivalent series resistance decreased, but the effects were influenced by duration of activation process.

  • 【文献出处】 材料工程 ,Journal of Materials Engineering , 编辑部邮箱 ,2004年02期
  • 【分类号】TB383
  • 【被引频次】9
  • 【下载频次】420
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