【摘要】 合成电子传输材料3,3′,5 三叔丁基 4,4′ 联苯醌总产率低的主要原因,在于3,3′,5 三叔丁基联苯酚的产率低。通过改变溶剂品种、催化剂AlCl3的用量、加料速度等优化了3,3′,5 三叔丁基联苯酚的合成条件,实验结果表明最终可将3,3′,5 三叔丁基 4,4′ 联苯醌的总产率从15%提高到33.6%。更多还原

【Abstract】 The main reason for the low gross yield of synthesis of electronic transport material 3, 3′,5-tri^tbutyl-4, 4′-diphenylquinone is the low yield of 3, 3′,5-tri^tbutyl-diphenol. In this paper,synthetic conditions optimization through change of solvents,the dose of AlCl₃ feeding rute and so on,is introduced.The result indicates that the 15% gross yield of 3,3′,5-tri^tbutyl-4,4′-diphenylquinone can be increased to 33.6%.更多还原