【摘要】 用Penning离子阱经碰撞反应H+ ,H+ 2 /H ,H2 产生稳定的H+ n(n =3,4 ,5 ,6 ) .高分辨离子谱中除了H+ ,H+ 2 ,H+ 3和H+ 5之外 ,还探测到H+ 4,H+ 6 .根据Wright和Borkman预言n =4 ,6的偶数氢团簇离子与对应的n =5 ,7的奇数离子具有可比较的结合能 ,由该实验结果可以推断 ,n =4 ,6与n =5 ,7的离子在反应动力学方面具有相近的性质 ,都能够经碰撞合成反应获得 .还分析了H+ 4,H+ 6的生成机制 .更多还原

【Abstract】 Steady H+ n(n=3,4,5,6)ion is produced by H+, H+ 2/H, H 2 collision reaction in a Penning ion trap. Except for H+, H+ 2, H+ 3 and H+ 5, H+ 4 and H+ 6 are detected in the ion spectrum of high difference ratio. Wright and Borkman predicted that H+ 4,6 have the comparable binding energy with the corresponding H+ 5,7. Our experimental results provide strong evidence to their prediction. It can be concluded from the experimental results that H+ 4,6 and the corresponding H+ 5,7 have the similar character in the aspect of reaction dynamics and they can be obtained by the collision compound reaction. The mechanism of the collision compound reaction H+ 4 and H+ 6 is also analysed.更多还原