【摘要】 文中通过溶剂热法合成无机 有机杂化材料Co2 (bpp) 4 V4O12 ·4H2 O(bpp为 1,3 联 (4 吡啶基 )丙烷 ) ,对影响溶剂热反应的主要因素如反应物摩尔比、反应温度、pH值等进行系统研究 ,确定了合成这种新型化合物的最佳条件。同时还比较说明刚性 4 ,4’ 联吡啶和柔性 1,2 二 (4 吡啶基 )乙烷和 1,3 二 (4 吡啶基 )丙烷对无机骨架的影响和Co2 (bpp) 4 V4O12 ·4H2 O晶体结构的新颖之处。更多还原

【Abstract】 In this paper, the reaction conditions such as the mole ratio, reaction temperature and the pH value were systematically investigated through the hydrothermal synthesis of Co 2(bpp) 4V 4O 12 ·4H 2O (bpp=1,3-bis(4-pyridyl)propane), and the optimum conditions of this reaction were determinated. At the same time, the influences of the rigid 4,4’-bipyridine and the flexible 1,2-bis(4-pyridyl)ethane and 1,3-bis(4-pyridyl)propane on the crystal structures were explored.更多还原