【摘要】 通过 1,4 二 (1 H 苯并三氮唑基 )丁烷 (L)与KSCN和Ni(NO3 ) 2 ·6H2 O或L与Cu(CH3 COO) 2 ·2H2 O自组装得到了两个配位聚合物 过元素分析 ,IR ,UV和热分析确定它们的化学式分别为 [NiL2 (NCS) 2 ]n(a)和[CuL(CH3 COO) 2 ]n(b) .更多还原

【Abstract】 By treating of 1,4-bis(1-H-benzotriazolyl)butane(L) and KSCN with Ni(NO 3) 2·6H 2O or Cu(CH 3COO) 2·2H 2O two novel coordination polymers [NiL 2(NCS) 2] n (a) and [CuL(CH 3COO) 2] n (b) are synthesized.They are characterized by means of elemental analysis, IR and TG-DTA. The results show that polymer (a) is a two-dimensional polymer and polymer (b) is a one-dimensional polymer.更多还原