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稀土元素对Sn-9Zn合金润湿性的影响

Wetting properties of Sn-9Zn solder alloy with trace rare earth elements

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【作者】 于大全赵杰王来

【Author】 YU Daquan, ZHAO Jie, WANG Lai (Department of Materials Engineering, Dalian University of Technology, Dalian 116024, China)

【机构】 大连理工大学材料工程系大连理工大学材料工程系 大连116024大连116024大连116024

【摘要】 Zn的活泼性使Sn 9Zn无铅钎料的润湿性和抗氧化性很差,在Sn 9Zn合金中加入适量混合稀土元素(Ce,La)可以改善其润湿性能。分别在245,260和290℃通过润湿平衡实验对钎料的润湿性进行了研究,并对RA,RMA,R和WWR4种不同钎剂进行了比较。结果表明:在运用活性松香钎剂时,微量混合稀土元素可以显著提高Sn 9Zn合金润湿性;而提高钎焊温度也可以改善润湿性能。

【Abstract】 The eutectic Sn9Zn alloy is one of the leadfree solder alloys at the present time. Since Zn is an active element in solder, the wetting and corrosion properties of Sn9Zn alloy are impaired. In order to improve the wetting behavior, trace rare earth elements were added into Sn9Zn alloy. The wetting balance tests were conducted in ambient air to reveal the wetting behavior. Several types of flux, i.e. RA, RMA, R and WWR, were used to study the wetting properties of the Sn9ZnRE alloy system at 245, 260 and 290 ℃, respectively. By using RA flux, the trace RE addition can improve the wetting behavior significantly and the increasing of the temperature can also improve the properties.

【关键词】 无铅钎料稀土Sn9Zn润湿性
【Key words】 lead-free solderrare earth elementSn-9Znwettability
【基金】 大连市科委计划项目资助(大科计发[2001]145)
  • 【文献出处】 中国有色金属学报 ,The Chinese Journal of Nonferrous Metals , 编辑部邮箱 ,2003年04期
  • 【分类号】TG425.1
  • 【被引频次】114
  • 【下载频次】613
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