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Ag-TCNQ薄膜电双稳态特性的XPS研究

XPS Study of Ag-TCNQ Electrical Bistable Films

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【作者】 张群孔令柱张强基王伟军华中一

【Author】 Zhang Qun,Kong Lingzhu,Zhang Qiangji *,Wang Weijun,Hua Zhongyi (Department of Materials Science,Fudan University,Shanghai,200433,China)

【机构】 复旦大学材料科学系复旦大学材料科学系 上海200433上海200433上海200433

【摘要】 本文采用X光电子谱仪 (XPS)研究了Ag TCNQ薄膜的电双稳态特性。对TCNQ粉末、热处理前后的TCNQ薄膜及Ag TCNQ薄膜作了分析。结果发现 ,真空蒸镀及大气环境中热处理不会引起TCNQ化学状态的变化 ,而热处理会促使Ag与TCNQ发生反应 ,薄膜电双稳态特性的优劣则与反应程度有关。最后讨论了这一现象的可能机理

【Abstract】 Electrical bistable characteristics in Ag TCNQ thin films was investigated with X ray photoelectron spectroscopy(XPS).TCNQ powder,TCNQ thin films and Ag TCNQ thin films with and without heat treatment were prepared and characterized.The results show that TCNQ keeps at the same chemical states during the processes of vacuum deposition and post heat treatment moderately in atmosphere.The reactions between Ag and TCNQ are accelerated by heat treatment,and the electrical switching properties are affected by the reaction degree.The possible mechanism has been briefly discussed.

【关键词】 XPSAg-TCNQ电双稳态特性化学态
【Key words】 XPSAg TCNQElectrical bistableChemical states
  • 【文献出处】 真空科学与技术 ,Vacuum Science and Technology , 编辑部邮箱 ,2003年03期
  • 【分类号】O484.5
  • 【被引频次】3
  • 【下载频次】104
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