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甲基丙烯酸对纳米SiO2微粒表面的原位聚合改性

Surface Modification of Nano-SiO2 by in-situ Polymerization of Methacrylic Acid

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【作者】 沈新璋金名惠

【Author】 SHEN Xin-Zhang, JIN Ming-Hui * (Department of Chemistry,Huazhong University of Science and Technology,Wuhan 430074)

【机构】 华中科技大学化学系华中科技大学化学系 武汉430074武汉430074

【Abstract】 Silane coupling agent was used to introduce polymerizable groups onto the surface of nano-SiO 2 particles. Then in-situ polymerization was carried out between the functionalized particles and methacrylic acid monmer to accomplish the surface modification of nano-SiO 2. Analysis of FTIR?TEM and TGA results show that methacrylic acid is grafted onto the surface of functionalized particles and the modified particles were stable. Contact angle measurement demonstrated that the modified particles were wetted by toluene completely and the contact angle with water was 105 ℃, indicating that the hydrophilic surface has been transfered to hydrophobic via the modification.

【基金】 华中科技大学研究生科技创新基金资助项目 (YCJ 0 2 0 0 8)
  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2003年10期
  • 【分类号】O631
  • 【被引频次】68
  • 【下载频次】488
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