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有序大孔TiO2的制备

Preparation of Ordered Macroporous Titania

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【作者】 匡代彬吴玉欧晃栋方岳平徐安武刘汉钦

【Author】 KUANG Dai-Bin, WU Yu, OU Huang-Dong, FANG Yue-Pin, XU An-Wu *, LIU Han-Qin (School of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou 510275)

【机构】 中山大学化学与化学工程学院中山大学化学与化学工程学院 广州510275广州510275广州510275

【Abstract】 The polystyrene(PS) microspheres were prepared from free radical polymerization of styrene by a sol-gel method combined with centrifugal sedimentation. And the ordered macroporous titania was prepared from Ti(BuO)4 in ethanol solution using the mentioned PS microspheres as a template, which was removed from titania by calcination at 450 ℃. SEM images revealed the PS template has a three-dimentional ordered structure with particle diameter of ca. 450 nm and the macroporous titania thus obtained has a pore size of ca. 300 nm. XRD showed the macroporous titania has anatase structure.

【基金】 广东省“十五重点”资助项目 (2 0 0 10 185 ;A30 40 30 2 )
  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2003年01期
  • 【分类号】O614
  • 【被引频次】15
  • 【下载频次】301
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