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Effects of Ce3+,Nd3+,Gd3+, Tb3+ and Lu3+ ions on Formation of CaCO3

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【作者】 黄健许善锦卢景芬王夔

【Author】 Huang Jian 1, Xu Shanjin 1* , Lu Jingfen 2, Wang Kui 2 (1. Department of Chemical Biology, School of Pharmaceutical Sciences, Peking University; 2. State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100083, China)

【机构】 Department of Chemical BiologySchool of Pharmaceutical SciencesPeking UniversityState Key Laboratory of Natural and Biomimetic DrugsPeking UniversityPeking University Beijing 100083ChinaBeijing 100083China

【Abstract】 The effects of lanthanides at various concentrations on CaCO 3 crystal growth were studied by X ray diffraction (XRD), infrared spectra (IR), X ray photoelectric energy spectra (XPS) and inductively coupled plasma mass spectrometry (ICP MS). It was found that the calcite, a stable form of CaCO 3 in thermodynamics, is the predominant species. The research indicates that lanthanide ions (Ln 3+ ) can partly substitute the Ca 2+ in the lattice of CaCO 3 crystals, and change the crystal characterization and direct the ordinal growth of CaCO 3 crystals.

【基金】 ProjectsupportedbytheNationalNaturalScienceFoundationofChina ( 2 98710 0 7)
  • 【文献出处】 Journal of Rare Earths ,稀土学报(英文版) , 编辑部邮箱 ,2003年03期
  • 【分类号】O782
  • 【被引频次】3
  • 【下载频次】69
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