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氨基磺酸催化合成对羟基苯甲酸丁酯
Synthesis of Butyl p-Hydroxy Benzoate by Aminosulfonic Acid
【摘要】 研究了以氨基磺酸为催化剂催化合成对羟基苯甲酸丁酯。优化反应条件如下:醇酸摩尔比为1:3.5,催化剂用量为1.6g(当对羟基苯甲酸用量为0.1mol 时),反应温度为135~140℃,反应时间3.0h,对羟基苯甲酸丁酯的产率为95.4%。催化剂易回收,可循环使用,不污染环境。
【Abstract】 The synthesis of butyl p-hydroxy benzoate with aminosulfonic acid as catalyst was studied.The optimum conditions were determined as follows:molar ratio of alcohol and acid was 3.5:1,amount of catalyst was 1.6g(when 0.1 mole of p-hydroxybenzoic acid was used)and temperature of reaction was 135~140℃,The yield of butyl p-hydroxy benzo- ate was 95.4.This catalyst had many advantage,such as easy to be recovered ,feasible to be used repeatedly and less pol- lution to environment.
【关键词】 氨基磺酸;
催化;
合成;
对羟基苯甲酸丁酯;
对羟基苯甲酸;
丁醇;
【Key words】 Aminosulfonic acid; Catalysis; Synthesis; Butyl p-hydroxy benzoate; p-Hydroxybenzoic acid; Butanol;
【Key words】 Aminosulfonic acid; Catalysis; Synthesis; Butyl p-hydroxy benzoate; p-Hydroxybenzoic acid; Butanol;
【基金】 广东工业大学青年基金资助项目(022029)
- 【文献出处】 香料香精化妆品 ,Flavour Fragrance Cosmetics , 编辑部邮箱 ,2003年05期
- 【分类号】TQ245.24
- 【被引频次】1
- 【下载频次】121