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糠醇生产中废弃物的循环回用新工艺

Recycling solid waste from production of furfuryl alcohol by furfural hydrogenization

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【作者】 李增新陈东辉王海增

【Author】 LI Zeng-xin 1,2, CHEN Dong-hui 2,WANG Hai-zeng 3 (1.College of Environmental Science and Engineering, Donghua University, Shanghai 200051, China; 2.Teachers College, Qingdao University, Qingdao 266071, China; 3.College of Chemical Engineering, Ocean University of China, Qingdao 266010, China)

【机构】 东华大学环境科学与工程学院青岛大学师范学院中国海洋大学化工学院 上海200051山东青岛266071山东青岛266010

【摘要】 将糠醛液相加氢生产糠醇产生的废渣置于真空干燥箱中 ,在较低的负压状态下保持 1 30℃的温度 ,蒸馏回收废渣中的有机物 ,返回糠醇精制车间获得合格的糠醇与糠醛产品 ;剩余的固体废弃物与纯碱混合 ,在反射炉中焙烧 ,浸取获得铬酸钠水溶液 ;最后剩下的粗氧化铜溶于硝酸得到硝酸铜溶液 ;将铬酸钠溶液、硝酸铜溶液按一定比例混合 ,加入氨水搅拌 ,分离出的沉淀经传统方法焙烧活化、造粒制得新催化剂 ,回用于糠醛液相加氢生产糠醇。铬组分和铜组分的回收率均在 90 %以上

【Abstract】 A new recovery technology of solid waste was made which is from furfuryl alcohol production by furfural hydrogenization.When the solid waste is placed in a vacuum drying box,and is under lower negative pressure and at 130℃,the organic materials in solid waste can be distilled and then returned to the refining workshop to produce qualified furfuraldehyde and furfuryl alcohol.The remainder is mixed with soda ash and roasted in a reverberating furnace.The sodium chromate can be obtained by leaching.Rough cupric oxide is dissolved in nitric acid and cupric nitrate is obtained.A new catalyst was prepared by the above sodium chromate and cupric nitrate and used in furfuryl alcohol production.The conversion rate of cupric and chromic ions can reach more than 90%.

【关键词】 糠醇废渣铜铬氧化物催化剂回收
【Key words】 furfuryl alcoholsolid wastecupric and chromic oxidecatalystrecovery
  • 【文献出处】 现代化工 ,Modern Chemical Industry , 编辑部邮箱 ,2003年08期
  • 【分类号】X783
  • 【被引频次】5
  • 【下载频次】225
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