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接触辉光放电等离子体降解水体中的对氯硝基苯
Degradation of p-chloronitrobenzene in aqueous solution by contact glow discharge electrolysis
【摘要】 接触辉光放电电解是一种新型的产生等离子体的电化学方法 .实验表明 ,利用该方法可将水体中的对氯硝基苯全部氧化为二氧化碳 .电压、浓度、催化剂对降解率有显著影响 ,pH值对降解无明显影响 .利用高效液相色谱检测了中间产物 ,推测了对氯硝基苯在接触辉光放电降解过程中的机理
【Abstract】 Contact glow discharge electrolysis is a novel type of electrochemical process.The results showed that p chloronitrobenzene was smoothly oxidized and eventually degraded to carbon dioxide.Concentration and voltage plays an important role,pH value has no appreciable effect on the degradation of p chloronitrobenzene,and Fe 2+ has a remarkable catalytic effect.Some of intermediate products were analyzed by a high performance liquid chromatography(HPLC).A path of p chloronitrobenzene disappearance caused by plasma was proposed according to the detected intermediate products.
【Key words】 contact glow discharge electrolysis; plasma; degradation; p chloronitrobenzene;
- 【文献出处】 西北师范大学学报(自然科学版) ,Journal of Northwest Normal University(Natural Science Edition) , 编辑部邮箱 ,2003年01期
- 【分类号】X703
- 【被引频次】51
- 【下载频次】275