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具有梯形结构钴(Ⅱ)配位聚合物的合成及晶体结构(英文)

Synthesis and Crystal Structure of a Novel Cobalt(Ⅱ) Coordination Polymer with Molecular Ladder Structure

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【作者】 吴杰颖潘月礼张宣军张明亮田玉鹏FUN Hoong-Kun

【Author】 WU Jie-Ying* ,1 PAN Yue- Li1 ZHANG Xuan- Jun2 ZHANG Ming- Liang1 TIAN Yu- Peng1,3 FUN Hoong-Kun4(1Department of Chemistry, Anhui University, Hefei 230039)(2Department of Chemistry, University of Science and Technology of China, Hefei 230026)(3State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093)(4X Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM, Penang, Malaysia)

【机构】 安徽大学化学化工学院中国科学技术大学化学系X-Ray Crystallography Unit School of PhysicsUniversiti Sains Malaysia 11800USMPenangMalaysia 合肥230039合肥230039合肥230026合肥230039南京大学配位化学国家重点实验室南京210093

【Abstract】 Co(NO3)2, N carbazolyacetic acid and 4,4′ bipyridyl can give rise to a novel coordination polymer [Co2(Cabo)2(NO3)2(4,4′ bipy)2]n using a fritted U tube. Single crystal X ray diffraction displays in the complex, each Co? is six coordinated by two N atoms from different 4,4′ bipyridyl ligands, two O atoms of the bridge from two N carbazolyacetic acid and two O atoms of one nitrate anion to form a distorted octahedral. Two O atoms of the carboxyl group act as bridge to link two Co? atoms. The resulting structure is a ladder polymer. CCDC: 211713.

【基金】 国家自然科学基金资助项目(No.20071001,50272001);安徽省自然科学基金资助项目(No.03044701);马来西亚科技大学研究基金资助项目(R&DNo.305/PFIZIK/61096)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2003年12期
  • 【分类号】O641.4
  • 【被引频次】1
  • 【下载频次】112
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