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ZnS准纳米棒的胶棉膜模板合成及其性能研究

Synthesis and Properties of ZnS Quasi- nanorods by Celloidin Membrane Template

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【作者】 刘金库吴庆生丁亚平

【Author】 LIU Jin-Ku1 WU Qing- Sheng* ,1 DING Ya- Ping2 (1Department of Chemistry, Tongji University, Shanghai 200092)(2Department of Chemistry, Shanghai University, Shanghai 200436)

【机构】 同济大学化学系上海大学化学系 上海200092上海200092上海200436

【Abstract】 ZnS Quasi nanorods were successfully synthesized with artificial active membrane of celloidin as template by the cooperating effect of artificial active membrane and ethylenediamine. The results indicated that ZnS quasi nanorods, which had a hexangular wurtzite structure, could be formed at room temperature with 0.1mol· L- 1 ZnSO4 which added suitable template reagent ethylenediamine and 0.1mol· L- 1 Na2S as reactants. The particles’ diameter was from 200nm to 500nm, and the average length was about 12μ m. The photics property study showed that the product reserved the properties of IR permeation and fluorescent luminescence in bulk materials, and the UV Vis spectrum showed that the furthest absorption peak was at 308nm having 42nm’s blue shift comparing to ZnS bulk material, which indicated that the particles had obvious quantum size effect.

【关键词】 胶棉模板硫化锌准纳米棒
【Key words】 celloidin template zinc sulfide quasi nanorods
【基金】 国家自然科学基金资助项目(No.20071025,20131030);上海市科技发展基金资助项目(No.0259nm021;0114nm004)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2003年12期
  • 【分类号】O614
  • 【被引频次】1
  • 【下载频次】105
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