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[Cu（TOL）₄]Cl₂·2C₂H₅OH·2H₂O的合成和晶体结构

Synthesis and Crystal Structure of [Cu（TOL）₄]Cl₂·2C₂H₅OH·2H₂O

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【Author】 ZHANG Pei Zhi* ,1 WU Jun2 GONG Yu Qiu2 HU Xiu Rong3 GU Jian Ming3(1Zhejiang University of Science and Technology, Department of Biological and Chemical Engineering, Hangzhou 310012)(2Zhejiang University, Department of Chemistry, Hangzhou 310027)(3The Central Laboratory, Zhejiang University, Hangzhou 310028)

【机构】浙江科技学院生物与化学工程学系；浙江大学化学系；浙江大学分析测试中心；浙江大学分析测试中心杭州310012；杭州310027；杭州310028；杭州310028；

【Abstract】 The complex of triadimenol(TOL) and copper chloride was synthesized in ethanol , and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to triclinic, space group , a=0.9861(2)nm, b=1.1930(2)nm, c=1.7140(3)nm, α =71.53(3)° , β =81.94(3)° , γ =75.56(3)° , V=1.848(6)nm3, Z=1, Dc=1.295g· cm- 3, F(000)=755, R1=0.0692, wR2=0.1845. The results show that the coordination geometry around copper? in the complex is slightly distorted four coordinated square planar geometry. The title complex was also characterized by elementary analysis, IR and TG. CCDC: 210089.更多还原

【关键词】三唑醇；铜(Ⅱ)配合物；合成；晶体结构；
【Key words】 triadimenol Cu? complex synthesis crystal structure；

【基金】浙江省自然科学基金(No.201004);浙江省教育厅基金(No.20010436)资助项目