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纳米TiO2-ZnO复合材料的合成、结构与光催化性能

Synthesis, Structure and Photocatalytic Property of Nano-TiO2-ZnO

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【作者】 丁士文王利勇张绍岩刘淑娟丁宇刘燕朝康全影

【Author】 DING Shi Wen*,1 WANG Li Yong1 ZHANG Shao Yan1 LIU Shu Juan1 DING Yu2 LIU Yan Chao1 KANG Quan Ying1 (1College of Chemistry and Environmental Science, 2College of Quantity Monitor, Hebei University, Baoding 071002)

【机构】 河北大学化学与环境科学学院河北大学质监学院河北大学化学与环境科学学院 保定071002保定071002保定071002

【Abstract】 Using ZnSO4 and TiCl4 as raw materials, nanometric TiO2 ZnO (ZnTiO3) is prepared at 180℃,0.8MPa by hydrothermal method. The effects of the reaction temperature and time on the nanometric TiO2 ZnO are also discussed. XRD shows that the product is TiO2 ZnO (ZnTiO3) with noncrystal phase, and it changes to rhombic form above 870℃. TEM measurement indicates that the TiO2 ZnO is spherical particles, and the average diameter of the particles is 20nm. The UV light absorption properties are detected by UV spectrophotometer. The results show that the nanometric TiO2 ZnO has strong absorption at 200~370nm and at visible region. Photodegradation of dyes in an aqueous solution is investigated using nanometric TiO2 ZnO as a photocatalyst. The results show that after 60min illumination, the decolorization rate of the acidic red B and acidic black 234 dye can be arrived at 100%.

【基金】 河北省自然科学基金资助项目(No.202104)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2003年06期
  • 【分类号】TB383
  • 【被引频次】127
  • 【下载频次】1131
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