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纳米氧化钕的制备及其催化性能的研究

Synthesis and Combustion Catalysis of Nanometer-sized Neodymium Oxide

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【作者】 徐宏蔡弘华罗仲宽任祥忠刘剑洪陈沛赵凤起田德余

【Author】 XU Hong*,1 CAI Hong-Hua1 LUO Zhong-Kuan1 REN Xiang-Zhong1 LIU Jian-Hong*,1 CHEN Pei2 ZHAO Feng-Qi2 TIAN De-Yu1,3 (1Department of Chemistry and Biology, Normal College, Shenzhen University, Shenzhen 518060) (2Xi’an Modern Chemistry Research Institute, Xi’an 710065) (3Institute of Aerospace and Material Engineering, National University of Defense Technology, Changsha 410073)

【机构】 深圳大学师范学院化生教育系西安近代化学研究所深圳大学师范学院化生教育系 深圳518060深圳518060西安710065深圳518060国防科技大学航天与材料工程学院长沙410073

【Abstract】 Nanometer sized neodymium oxide has been synthesized by humid solid state reaction at room temperature, and characterized by scanning electron microscope, laser light scattering and X ray diffraction. The effects of nanometer sized neodymium oxide on catalyzing thermal decomposition reaction of hexogen (cyclotrimethylenetriamine, RDX) and absorbent powder (nitrocellulose absorbed nitroglycerin, NC/NG) have been investigated by DSC method. The mechanism of these catalytic reactions has also been proposed. The experimental results show that nanometer sized neodymium oxide can catalyze the decomposition reaction of RDX and NC/NG effectively. The experimental results further suggest that nanometer sized neodymium oxide is a potentially useful combustion catalyst of nitroamine propellant.

【基金】 高等学校骨干教师资助计划项目(No.教育育部科技司犤2000犦65号)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2003年06期
  • 【分类号】TB383
  • 【被引频次】52
  • 【下载频次】521
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