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TiO2/SnO2复合薄膜的亲水性能研究

Super-hydrophilicity of TiO2/SnO2 Composite Film

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【作者】 柳清菊杨喜昆刘强王宝玲吴兴惠

【Author】 LIU Qing-Ju, YANG Xi-Kun, LIU Qiang, WANG Bao-Ling, WU Xing-Hui(Department of Material Science & Engineering, Yunnan University, Kunming 650091, China;Yunnna Analysis Test Center, Kunming 650091, China)

【机构】 云南大学材料科学与工程系云南省分析测试中心云南大学材料科学与工程系 昆明 650091

【摘要】 采用溶胶-凝胶法制备了TiO2/SnO2复合薄膜,通过XRD、XPS、UV透射光谱的分析及薄膜表面接触角、光催化降解甲基橙等的分析,研究了SnO2与TiO2配比、热处理温度、膜厚度等因素对复合膜的亲水性、透光率及光催化活性的影响.结果表明:复合膜的亲水性和光催化活性均优于单纯TiO2,当SnO2与TiO2的摩尔比为1%~5%时,所制备的薄膜具有超亲水特性;热处理温度为450℃时薄膜亲水性最好,膜厚度的增加有利于亲水性的改善.

【Abstract】 TiO2/SnO2 composite thin films were prepared on soda-lime glass with the sol-gel method. The influence of SnO2 doping concentration, heat-treatment temperature and film thickness on the super-hydrophilicity and photocatalytic activity of the composite films was studied by XRD, XPS, UV-spectra, measuring the contact angle and the degradation of methyl orange. The results indicate that the doping of SnO2 into TiO2 can improve their hydrophilicity and photocatalytic activity, and the composite film with 1%-5% SnO2 and heat-treated at 450℃ is of super-hydrophilicity. The optimal SnO2 concentration for the photocatalytic activity is 10% and larger film thickness is helpful to reduce the contact angle of the composite films.

【基金】 国家自然科学基金(50162002);云南省自然科学重点基金(2000E0002Z);云南省中青年学术带头人后备人才项目(2000YP29)
  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2003年06期
  • 【分类号】O484
  • 【被引频次】18
  • 【下载频次】218
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